Steve Clarke’s men beat Curacao 4-1 at Hampden Park in Glasgow before jetting out to North America to prepare for the upcoming tournament.
The Scots will face their South American opponents at the Sports Illustrated Stadium in Harrison, New Jersey, which is the home of the New York Red Bulls, the Major League Soccer franchise.
Scotland are playing in their first World Cup since Craig Brown guided them to the 1998 tournament, and they have a tough group to try and get out of.
First, they face Haiti, the weakest in Group C, at the Gillette Stadium in Foxborough, Massachusetts, before they take on Morocco in their next match.
Their trickiest test will come on matchday three against Brazil, at the Hard Rock Stadium in Miami, Florida.
The furthest Scotland have gone at a World Cup is the group stage, but they will be hoping to write history in the United States this time around.
How to watch Bolivia vs Scotland
TV channel: You can watch Bolivia vs Scotland live and for free on BBC Two, with coverage starting at 8.30pm BST ahead of the 9pm kick off.
Live stream: You can also stream the game for free on BBC iPlayer with a valid TV licence.
